{"id":622,"date":"2024-02-09T10:07:25","date_gmt":"2024-02-09T09:07:25","guid":{"rendered":"https:\/\/clic.chimie.unistra.fr\/?page_id=622"},"modified":"2024-02-09T15:55:30","modified_gmt":"2024-02-09T14:55:30","slug":"halogen-and-chalcogen-bond-in-catalysis-2","status":"publish","type":"page","link":"https:\/\/clic.chimie.unistra.fr\/?page_id=622","title":{"rendered":"Halogen and Chalcogen Bond in Catalysis"},"content":{"rendered":"

Halogen and Chalcogen Bond in Catalysis<\/strong><\/p>\n

We study s-hole interactions in solution and we develop new chiral halogen and chalcogen bond donors for application in (asymmetric) catalysis.<\/p>\n

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Halogen and Chalcogen Bond Donors Based on Axially Chiral 4,4′-bipyridine Scaffold <\/strong><\/p>\n

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Halogen Bond Donors Based on Planar Chiral Ferrocenyl Scaffold <\/strong><\/p>\n

Chalcogen Bond Donors Based on Tellurium <\/strong><\/p>\n

Study in Solution<\/em><\/strong><\/p>\n

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Catalysis<\/em><\/strong><\/p>\n

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\u00a0<\/u><\/p>\n

Selected publications:<\/u><\/p>\n

1) Weiss, R.; Aubert, E.; Peluso, P.; Cossu, S.; Pale, P.; Mamane, V. Chiral Chalcogen Bond Donors Based on the 4,4\u2019-Bipyridine Sca\ufb00old. Molecules<\/em> 2019<\/strong>, 24<\/em>, 4484.<\/a><\/span><\/p>\n

2) Mamane, V.; Peluso, V.; Aubert, E.; Weiss, R.; Wenger, E.; Cossu, S. Pale, P. Disubstituted Ferrocenyl Iodo- and Chalcogenoalkynes as Chiral Halogen and Chalcogen Bond Donors. Organometallics<\/em> 2020<\/strong>, 39<\/em>, 3936.<\/a><\/span><\/p>\n

3) Weiss, R.; Aubert, E.; Pale, P.; Mamane, V. Chalcogen-Bonding Catalysis with Telluronium Cations. Angew. Chem. Int. Ed.<\/em> 2021<\/strong>, 60<\/em>, 19281.<\/a><\/span><\/p>\n

4) Weiss, R.; Golisano, T.; Pale, P.; Mamane, V. Insight into the Modes of Activation of Pyridinium and Bipyridinium Salts in Non-Covalent Organocatalysis. Adv. Synth. Catal.<\/em> 2021<\/strong>, 363<\/em>, 4779.<\/a><\/span><\/p>\n

5) Aubert, E., Doudouh, A., Wenger, E.; Sechi, B.; Peluso, P.; Pale, P.; Mamane, V. Chiral Ferrocenyl\u2013Iodotriazoles and \u2013Iodotriazoliums as Halogen Bond Donors. Synthesis, Solid State Analysis and Catalytic Properties. Eur. J. Inorg. Chem.<\/em> 2022<\/strong>, 2022<\/em>, e202100927.<\/a><\/span><\/p>\n

6) Weiss, R.; Aubert, E.; Groslambert, L.; Pale, P.; Mamane, V. Chalcogen Bonding with Diaryl Ditellurides: Evidence from Solid State and Solution Studies. Chem. Eur. J.<\/em> 2022<\/strong>, 28<\/em>, e202200395 (Hot Paper).<\/a><\/span><\/p>\n

7) Peluso, P.; Mamane, V. Stereoselective Processes Based on \u03c3-Hole Interactions. Molecules<\/em> 2022<\/strong>, 27<\/em>, 4625 (Review).<\/a><\/span><\/p>\n

8) Pale, P.; Mamane, V. Chalcogen Bonds: How to Characterize Them in Solution? ChemPhysChem<\/em> 2023<\/strong>, 24<\/em>, e202200481 (Concept Article).<\/a><\/span><\/p>\n

9) <\/span>Groslambert, L.; Padilla-Hernandez, A.; Weiss, R.; Pale, P.; Mamane, V. Chalcogen-Bond Catalysis: Telluronium-Catalyzed [4+2]-Cyclocondensation of (in situ Generated) Aryl Imines with Alkenes. Chem. Eur. J.<\/em> 2023<\/strong>, 29, e202203372 (Hot Paper).<\/span><\/a><\/p>\n

10) Pale, P.; Mamane, V. Chalcogen bonding catalysis: tellurium, the last frontier? Chem. Eur. J.<\/em> 2023<\/strong>, 29<\/em>, e202302755 (Review).<\/p>\n

11) Weiss, R.; Aubert, E.; Groslambert, L.; Pale, P.; Mamane, V. Evidence for and evaluation of fluorine\u2013tellurium chalcogen bonding. Chem. Sci.<\/em> 2023<\/strong>, 14<\/em>, 7221.<\/p>\n

12) Groslambert, L.; Cornaton, Y.; Ditte, M.; Aubert, E.; Pale, P.; Tkatchenko, A.; Djukic, J.-P.; Mamane, V. Affinity of Telluronium Chalcogen Bond Donors for Lewis Bases in Solution: A Critical Experimental-Theoretical Joint Study. Chem. Eur. J.<\/em> 2024<\/strong>, 30<\/em>, e202302933 (Very Important Paper).<\/p>\n

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Halogen and Chalcogen Bond in Catalysis We study s-hole interactions in solution and we develop new chiral halogen and chalcogen bond donors for application in (asymmetric) catalysis. Halogen and Chalcogen… Read More<\/a><\/span><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-622","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/clic.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/pages\/622","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/clic.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/clic.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/clic.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/clic.chimie.unistra.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=622"}],"version-history":[{"count":2,"href":"https:\/\/clic.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/pages\/622\/revisions"}],"predecessor-version":[{"id":628,"href":"https:\/\/clic.chimie.unistra.fr\/index.php?rest_route=\/wp\/v2\/pages\/622\/revisions\/628"}],"wp:attachment":[{"href":"https:\/\/clic.chimie.unistra.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=622"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}